Runway Trailblazers

A handful of people--namely sought-after celebrities and tastemakers like Jessica Alba, Kerry Washington, and Kirsten Dunst--are able to do what many of us only dream about: wear a head-to-toe ensemble straight off the runway. Of course, these trailblazers possess coveted access to these designer looks, but they have certainly got the panache to pull off these avant-garde styles too. Thanks to their dare-to-wear attitude, these fashionable ladies--attired in everything from Louis Vuitton's graphic checks or Peter Pilotto's 3-D ruffles--pave the way for the rest of us to experiment with the latest trends. Continue reading to see who wore striking outfits from the S/S 13 collections and looked like a smashing success!--Tiffany Tse1. Jessica Alba
Louis Vuitton Damier Sequins Dress (price upon request, 866.VUITTON)

2. Naomi Watts
Calvin Klein Collection Reed Matte Satin/Sheer Silk Dress ($4995, 212.292.9000) and Black Satin Faceted Platform Sandals ($1495, 212.292.9000)

3. Sienna Miller
Isabel Marant Natacha Dress ($525, 323.651.1493)

4. Rachel Weisz
Bottega Veneta Appia Poussin Silk Embroidered Studded Marguerite Print Dress ($2600, available at Bottega Veneta boutiques)

5. Allison Williams
Altuzarra Binta Bustier With Scalloped Embroidery ($1195) and Tempest Skirt With Patchwork Seams (price upon request)

6. Anna Dello Russo
Prada Mink Flower Top ($19930) and Silk Satin Skirt ($1460)

7. Rose Byrne
Diane von Furstenberg custom-made Navy Blue Silk Embellished Top and Matching Pants

8. Kerry Washington
Peter Pilotto Lara Dress ($4395)

9. Elle Fanning
Chanel White Strapless Dress With Flower Applique (price upon request, 800.550.0005)

10. Anne Hathaway
Saint Laurent by Hedi Slimane Tuxedo Jacket ($2950, 212.980.2970), Vest ($990, 212.980.2970), Blouse ($1750, 212.980.2970), and Pants ($1150, 212.980.2970)

11. Kirsten Dunst
Louis Vuitton Scuba Small Damier Dress (price upon request, 866.VUITTON)

Photos of Anna Dello Russo, Jessica Alba, Kerry Washington, Rachel Weisz, Rose Byrne, Sienna Miller, courtesy of Getty Images; photo of Diane Kruger, courtesy of Splash News; photo of Anne Hathaway, courtesy of Startraks.